Abstract: The unconventional emergencies make our human beings suffer increasingly serious economic loss and casualties. A proper decision is turned out to be the most important thing to reduce the loss and save the casualties. But traditional emergency decision-making model is not suitable for the unconventional emergencies. In this paper, the application of experience to unconventional emergency decision-making is discussed. Firstly, the existence and importance of the application of experience to unconventional emergency decision-making are highlighted according to some important conclusions of intuitive decision-making theory and naturalistic decision-making theory. Secondly, through analyzing how “experience” can affect “emergency decision making”, the advantages of applying “experience” to “unconventional emergency decision-making” are illustrated. Lastly, from the perspective of “experience-research”, several possible further research topics are put forward.